Kp = Kc (RT)^Δn
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Kp and Kc are equilibrium constants for gas-phase reactions. Kc is based on concentrations (mol/L), while Kp is based on partial pressures (atm). The relationship between them is given by the formula Kp = Kc (RT)^Δn.
The calculator uses the formula:
Where:
Explanation: The equation converts between concentration-based and pressure-based equilibrium constants using the ideal gas law relationship.
Details: Calculating Kp from Kc is essential for understanding gas-phase equilibria and for comparing equilibrium constants measured under different conditions.
Tips: Enter Kc (unitless), R (typically 0.0821 L atm/mol K), temperature in Kelvin, and Δn (change in moles of gas). All values must be valid.
Q1: What is Δn in the formula?
A: Δn is the difference between the sum of stoichiometric coefficients of gaseous products and reactants (Δn = Σn_products - Σn_reactants).
Q2: When should I use Kp instead of Kc?
A: Use Kp when dealing with gas-phase reactions where partial pressures are more convenient or measurable than concentrations.
Q3: What are typical values for Kp and Kc?
A: Both can range from very small to very large values, indicating the extent of reaction at equilibrium.
Q4: Are there limitations to this conversion?
A: This conversion assumes ideal gas behavior and may not be accurate at high pressures or for real gases.
Q5: Can this be used for reactions involving both gases and other phases?
A: The conversion only applies to gaseous components. Solids and liquids are not included in Δn calculations.